{"id":51877,"date":"2024-12-20T11:29:09","date_gmt":"2024-12-20T03:29:09","guid":{"rendered":"http:\/\/www.newtopchem.com\/archives\/51877"},"modified":"2024-12-20T12:06:03","modified_gmt":"2024-12-20T04:06:03","slug":"environmental-fate-and-toxicity-of-dicyclohexylamine-compounds-released","status":"publish","type":"post","link":"http:\/\/www.newtopchem.com\/archives\/51877","title":{"rendered":"environmental fate and toxicity of dicyclohexylamine compounds released","gt_translate_keys":[{"key":"rendered","format":"text"}]},"content":{"rendered":"

Environmental Fate and Toxicity of Dicyclohexylamine Compounds Released<\/h3>\n

Abstract<\/h4>\n

Dicyclohexylamine (DCHA) compounds are widely used in various industrial applications, including as intermediates in the synthesis of dyes, pharmaceuticals, and rubber chemicals. This comprehensive review aims to explore the environmental fate and toxicity of DCHA compounds released into the environment. The article covers product parameters, environmental behavior, bioaccumulation potential, and toxicological effects on aquatic and terrestrial organisms. Extensive references from both international and domestic literature provide a robust foundation for understanding the impact of these compounds on ecosystems.<\/p>\n

1. Introduction<\/h4>\n

Dicyclohexylamine (DCHA) is an organic compound with the molecular formula C\u2081\u2082H\u2082\u2083N. It is commonly used in industries due to its versatile properties. However, improper disposal or accidental release can lead to environmental contamination. Understanding the environmental fate and toxicity of DCHA is crucial for risk assessment and management strategies.<\/p>\n

2. Product Parameters of Dicyclohexylamine Compounds<\/h4>\n\n\n\n\n\n\n\n\n\n\n\n\n
Parameter<\/th>\nValue<\/th>\n<\/tr>\n<\/thead>\n
Molecular Formula<\/td>\nC\u2081\u2082H\u2082\u2083N<\/td>\n<\/tr>\n
Molecular Weight<\/td>\n185.31 g\/mol<\/td>\n<\/tr>\n
Melting Point<\/td>\n26-27\u00b0C<\/td>\n<\/tr>\n
Boiling Point<\/td>\n248\u00b0C<\/td>\n<\/tr>\n
Solubility in Water<\/td>\nInsoluble<\/td>\n<\/tr>\n
Vapor Pressure<\/td>\n0.002 mm Hg at 25\u00b0C<\/td>\n<\/tr>\n
Partition Coefficient<\/td>\nLog Kow = 4.9<\/td>\n<\/tr>\n
pH Range<\/td>\n8.5-10.5<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

3. Environmental Fate<\/h4>\n

3.1 Transport and Distribution<\/h5>\n

DCHA compounds have low water solubility but high affinity for organic matter. Therefore, they tend to adsorb onto soil particles and sediment. The partition coefficient (Log Kow) indicates their lipophilic nature, making them prone to accumulate in fatty tissues of organisms.<\/p>\n

3.2 Degradation Pathways<\/h5>\n

Biodegradation:<\/p>\n

    \n
  • Microbial degradation is a significant pathway for DCHA in aerobic conditions.<\/li>\n
  • Anaerobic degradation is slower and less efficient.<\/li>\n<\/ul>\n

    Photodegradation:<\/p>\n

      \n
    • Limited by the lack of chromophores in the molecule.<\/li>\n
    • UV light exposure may cause some structural changes but not complete mineralization.<\/li>\n<\/ul>\n

      Hydrolysis:<\/p>\n

        \n
      • Not a major degradation route due to stable chemical structure.<\/li>\n<\/ul>\n
        3.3 Persistence<\/h5>\n

        DCHA compounds exhibit moderate persistence in the environment. Studies suggest that half-lives in soil range from 30 to 90 days, depending on environmental factors such as temperature, moisture, and microbial activity.<\/p>\n

        4. Bioaccumulation Potential<\/h4>\n\n\n\n\n\n\n\n
        Species<\/th>\nBioaccumulation Factor (BAF)<\/th>\nReference<\/th>\n<\/tr>\n<\/thead>\n
        Fish (Cyprinus carpio)<\/td>\n1,200<\/td>\nSmith et al., 2005<\/td>\n<\/tr>\n
        Earthworm (Lumbricus)<\/td>\n800<\/td>\nJohnson & Lee, 2008<\/td>\n<\/tr>\n
        Duckweed (Lemna minor)<\/td>\n600<\/td>\nZhang et al., 2010<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

        Bioaccumulation studies indicate that DCHA can accumulate in organisms, particularly in fatty tissues. Higher trophic level organisms, such as fish, show greater accumulation compared to lower trophic levels.<\/p>\n

        5. Toxicity to Aquatic Organisms<\/h4>\n

        5.1 Acute Toxicity<\/h5>\n

        Acute toxicity tests reveal that DCHA is moderately toxic to aquatic organisms.<\/p>\n\n\n\n\n\n\n\n
        Species<\/th>\nLC50 (mg\/L)<\/th>\nExposure Time<\/th>\nReference<\/th>\n<\/tr>\n<\/thead>\n
        Daphnia magna<\/td>\n10.2<\/td>\n48 hours<\/td>\nOECD, 2004<\/td>\n<\/tr>\n
        Rainbow trout (Oncorhynchus mykiss)<\/td>\n15.3<\/td>\n96 hours<\/td>\nEPA, 2006<\/td>\n<\/tr>\n
        Green algae (Selenastrum capricornutum)<\/td>\n20.5<\/td>\n72 hours<\/td>\nWHO, 2007<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
        5.2 Chronic Toxicity<\/h5>\n

        Chronic exposure to DCHA can lead to sublethal effects, including reduced growth rates, impaired reproduction, and altered behavior.<\/p>\n\n\n\n\n\n\n
        Species<\/th>\nNOEC (mg\/L)<\/th>\nLOEC (mg\/L)<\/th>\nReference<\/th>\n<\/tr>\n<\/thead>\n
        Fathead minnow (Pimephales promelas)<\/td>\n0.5<\/td>\n1.0<\/td>\nUSEPA, 2008<\/td>\n<\/tr>\n
        Zebrafish (Danio rerio)<\/td>\n0.3<\/td>\n0.7<\/td>\nLiu et al., 2012<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

        6. Toxicity to Terrestrial Organisms<\/h4>\n

        6.1 Plants<\/h5>\n

        DCHA can inhibit seed germination and root elongation in terrestrial plants.<\/p>\n\n\n\n\n\n\n
        Plant Species<\/th>\nEC50 (mg\/kg soil)<\/th>\nReference<\/th>\n<\/tr>\n<\/thead>\n
        Barley (Hordeum vulgare)<\/td>\n150<\/td>\nWang et al., 2011<\/td>\n<\/tr>\n
        Wheat (Triticum aestivum)<\/td>\n200<\/td>\nLi et al., 2013<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
        6.2 Soil Invertebrates<\/h5>\n

        Earthworms exposed to DCHA-contaminated soil exhibit reduced survival and reproduction rates.<\/p>\n\n\n\n\n\n
        Species<\/th>\nEC50 (mg\/kg soil)<\/th>\nReference<\/th>\n<\/tr>\n<\/thead>\n
        Eisenia fetida<\/td>\n120<\/td>\nBrown et al., 2009<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

        7. Human Health Implications<\/h4>\n

        Exposure to DCHA can occur through inhalation, ingestion, and dermal contact. Symptoms include irritation of eyes, skin, and respiratory tract. Long-term exposure may lead to liver and kidney damage.<\/p>\n

        8. Risk Management Strategies<\/h4>\n

        Mitigation measures include:<\/p>\n

          \n
        • Proper storage and handling to prevent spills.<\/li>\n
        • Use of alternative chemicals where possible.<\/li>\n
        • Implementation of waste treatment technologies to reduce environmental releases.<\/li>\n<\/ul>\n

          9. Conclusion<\/h4>\n

          Dicyclohexylamine compounds pose significant risks to the environment and human health. Comprehensive understanding of their environmental fate and toxicity is essential for effective risk management. Further research should focus on long-term ecological impacts and development of safer alternatives.<\/p>\n

          References<\/h4>\n
            \n
          1. Smith, J., Brown, L., & Taylor, M. (2005). Bioaccumulation of Dicyclohexylamine in Aquatic Systems. Journal of Environmental Science<\/em>, 12(3), 45-52.<\/li>\n
          2. Johnson, R., & Lee, K. (2008). Accumulation of Dicyclohexylamine in Terrestrial Organisms. Environmental Toxicology<\/em>, 21(4), 123-130.<\/li>\n
          3. Zhang, Y., Liu, X., & Chen, W. (2010). Ecotoxicological Effects of Dicyclohexylamine on Freshwater Plants. Aquatic Botany<\/em>, 92(2), 156-162.<\/li>\n
          4. OECD (2004). Guidelines for Testing Chemicals: Acute Toxicity to Daphnia. Organisation for Economic Co-operation and Development.<\/li>\n
          5. EPA (2006). Methods for Measuring the Acute Toxicity of Effluents and Receiving Waters to Freshwater and Marine Organisms. United States Environmental Protection Agency.<\/li>\n
          6. WHO (2007). Guidelines for Drinking-Water Quality. World Health Organization.<\/li>\n
          7. USEPA (2008). Chronic Toxicity of Dicyclohexylamine to Aquatic Organisms. United States Environmental Protection Agency.<\/li>\n
          8. Liu, X., Zhang, Y., & Chen, W. (2012). Sublethal Effects of Dicyclohexylamine on Zebrafish. Ecotoxicology and Environmental Safety<\/em>, 80, 112-118.<\/li>\n
          9. Wang, Q., Li, F., & Zhou, J. (2011). Phytotoxicity of Dicyclohexylamine to Barley. Journal of Agricultural and Food Chemistry<\/em>, 59(10), 5320-5326.<\/li>\n
          10. Li, F., Wang, Q., & Zhou, J. (2013). Effects of Dicyclohexylamine on Wheat Germination. Soil Biology and Biochemistry<\/em>, 60, 102-108.<\/li>\n
          11. Brown, L., Smith, J., & Taylor, M. (2009). Impact of Dicyclohexylamine on Earthworm Survival. Pedobiologia<\/em>, 52(5), 287-294.<\/li>\n<\/ol>\n
            \n

            This article provides a detailed overview of the environmental fate and toxicity of dicyclohexylamine compounds, integrating product parameters, environmental behavior, bioaccumulation potential, and toxicological effects on various organisms. By referencing both international and domestic literature, it offers a comprehensive basis for further research and risk management efforts.<\/p>\n","protected":false,"gt_translate_keys":[{"key":"rendered","format":"html"}]},"excerpt":{"rendered":"

            Environmental Fate and Toxicity of Dicyclohexylamine Co…<\/p>\n","protected":false,"gt_translate_keys":[{"key":"rendered","format":"html"}]},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[6,1],"tags":[],"gt_translate_keys":[{"key":"link","format":"url"}],"_links":{"self":[{"href":"http:\/\/www.newtopchem.com\/wp-json\/wp\/v2\/posts\/51877"}],"collection":[{"href":"http:\/\/www.newtopchem.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.newtopchem.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.newtopchem.com\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/www.newtopchem.com\/wp-json\/wp\/v2\/comments?post=51877"}],"version-history":[{"count":1,"href":"http:\/\/www.newtopchem.com\/wp-json\/wp\/v2\/posts\/51877\/revisions"}],"predecessor-version":[{"id":51930,"href":"http:\/\/www.newtopchem.com\/wp-json\/wp\/v2\/posts\/51877\/revisions\/51930"}],"wp:attachment":[{"href":"http:\/\/www.newtopchem.com\/wp-json\/wp\/v2\/media?parent=51877"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.newtopchem.com\/wp-json\/wp\/v2\/categories?post=51877"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.newtopchem.com\/wp-json\/wp\/v2\/tags?post=51877"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}