{"id":48047,"date":"2024-04-25T16:04:41","date_gmt":"2024-04-25T08:04:41","guid":{"rendered":"http:\/\/www.newtopchem.com\/archives\/48047"},"modified":"2024-04-25T16:04:41","modified_gmt":"2024-04-25T08:04:41","slug":"methoxychlorine","status":"publish","type":"post","link":"http:\/\/www.newtopchem.com\/archives\/48047","title":{"rendered":"Methoxychlorine","gt_translate_keys":[{"key":"rendered","format":"text"}]},"content":{"rendered":"<p><img decoding=\"async\" loading=\"lazy\" class=\"alignnone size-full wp-image-48046\" src=\"http:\/\/www.newtopchem.com\/wp-content\/uploads\/2024\/04\/32eb3db3cb5b4017bb7305992fbb5d5a.gif\" width=\"336\" height=\"227\" alt=\"Methoxychlorine structural formula\" \/><\/p>\n<p>Structural formula<\/p>\n<table class=\"summary-table table table-striped table-bordered\">\n<col width=\"90\" \/>\n<tbody>\n<tr>\n<th scope=\"row\">Business number<\/th>\n<td>01H1<\/td>\n<\/tr>\n<tr>\n<th scope=\"row\">Molecular formula<\/th>\n<td>C16H15Cl3O2<\/td>\n<\/tr>\n<tr>\n<th scope=\"row\">Molecular weight<\/th>\n<td>345.65<\/td>\n<\/tr>\n<tr>\n<th scope=\"row\">label<\/th>\n<td>\n<p>                         1,1,1-Trichloro-2,2-bis-p-methoxyphenylethane,<\/p>\n<p>                         1,1,1-Trichloro-2,2-bis(4-methoxyphenyl)ethane,<\/p>\n<p>                         methoxychlor,<\/p>\n<p>                         Marlate,Metox,<\/p>\n<p>                         1,1,1-Trichloro-2,2-di(4-methoxyphenyl)ethane,<\/p>\n<p>                         2,2-Bis(4-methoxyphenyl)-1,1,1-trichloroethane,<\/p>\n<p>                         DMDT,<\/p>\n<p>                         Organochlorine pesticides<\/p>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<ul class=\"nav nav-tabs\">\n<li class=\"active\"><a href=\"#bh\">Numbering system<\/a><\/li>\n<li><a href=\"#wx\">Physical property data<\/a><\/li>\n<li><a href=\"#dl\">Toxicological data<\/a><\/li>\n<li><a href=\"#st\">Ecological data<\/a><\/li>\n<li><a href=\"#fz\">Molecular structure data<\/a><\/li>\n<li><a href=\"#js\">Computing chemical data<\/a><\/li>\n<li class=\"dropdown pull-right\">\n                     <a href=\"\" class=\"dropdown-toggle\">More <span class=\"caret\"><\/span><\/a><\/p>\n<ul class=\"dropdown-menu\" role=\"menu\">\n<li><a href=\"#xz\">Properties and Stability<\/a><\/li>\n<li><a href=\"#zc\">Storage method<\/a><\/li>\n<li><a href=\"#hc\">Synthesis method<\/a><\/li>\n<li><a href=\"#yt\">Purpose<\/a><\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<h2 id=\"bh\">Numbering system<\/h2>\n<p><b>CAS number:<\/b>72-43-5<\/p>\n<p><b>MDL number:<\/b>MFCD00000803<\/p>\n<p><b>EINECS number:<\/b>200-779-9<\/p>\n<p><b>RTECS number:<\/b>KJ3675000<\/p>\n<p><b>BRN number:<\/b>2057367<\/p>\n<p><b>PubChem number:<\/b>24896655<\/p>\n<h2 id=\"wx\">Physical property data<\/h2>\n<p><p>1. Properties: The original drug is white or creamy yellow block or flake solid<\/p>\n<p>2. Density (g\/mL, 25\/4\u2103): 1.41<\/p>\n<p>3  . Relative vapor density (g\/mL, air=1): Uncertain<\/p>\n<p>4. Melting point (\u00baC): 86-88 (pure product), industrial product is about 77\u2103<\/p>\n<p>5. Boiling point (\u00baC, normal pressure): Uncertain<\/p>\n<p>6. Boiling point (\u00baC, 5.2 kPa): Uncertain<\/p>\n<p>7. Refractive index: Uncertain<\/p>\n<p>8. Flash point (\u00baC): 11<\/p>\n<p>9. Specific rotation (\u00ba): Uncertain<\/p>\n<p>10. Autoignition point or ignition temperature (\u00baC): Uncertain  Confirm<\/p>\n<p>11. Vapor pressure (kPa, 25 \u00baC): Uncertain<\/p>\n<p>12. Saturated vapor pressure (kPa, 60 \u00baC): Uncertain<\/p>\n<p>13  . Heat of combustion (KJ\/mol): Uncertain<\/p>\n<p>14. Critical temperature (\u00baC): Uncertain<\/p>\n<p>15. Critical pressure (KPa): Uncertain<\/p>\n<p>16. Log value of oil-water (octanol\/water) partition coefficient: Uncertain<\/p>\n<p>17. Explosion upper limit (%, V\/V): Uncertain<\/p>\n<p>18. Explosion  Lower limit (%, V\/V): Uncertain<\/p>\n<p>19. Solubility: Easily soluble in benzene, xylene and other organic solvents, soluble in ethanol and petroleum, insoluble in water (0.1mg  \/L)<\/p>\n<\/p>\n<h2 id=\"dl\">Toxicological data<\/h2>\n<p>\n     <span style=\"font-family:Arial\">Acute oral administration in rats<span style=\"font-family:Arial\">LD50<\/span> &gt; 10000mg\/kg (6000mg\/kg), acute oral administration in rats  Skin<span style=\"font-family:Arial\">LD50<\/span> &gt;10000mg\/kg.  The no-effect dose in rats was 500 mg\/kg for 30 days, and the no-effect dose in the 2-year feeding test was 200 mg\/kg. The no-effect dose in the 1-year feeding test for dogs was 300 mg\/kg. Animal tests showed no teratogenic, carcinogenic, or mutagenic effects.  Mallard<span style=\"font-family:Arial\">LD50<\/span> &gt;2000mg \/kg &gt; Crane and quail &gt; 5000mg \/kg &gt; Pheasant &gt; 5000mg \/kg.  Rainbow cicada<span style=\"font-family:Arial\">LC50<\/span> is 45<span style=\"font-family:Arial\">\u03bc<\/span>g\/L (24h), bee LDS  .  It is 165.5<span style=\"font-family:Arial\">\u03bc<\/span>g\/piece.  <\/span>\n     <\/p>\n<h2 id=\"st\">Ecological data<\/h2>\n<p>\n     None\n     <\/p>\n<h2 id=\"fz\">Molecular structure data<\/h2>\n<p>\n     None\n     <\/p>\n<h2 id=\"js\">Compute chemical data<\/h2>\n<p><p>1. Reference value for hydrophobic parameter calculation (XlogP): None<\/P><\/p>\n<p>2. Number of hydrogen bond donors: 0<\/p>\n<p>3. Number of hydrogen bond acceptors: 2<\/p>\n<p>4. Number of rotatable chemical bonds: 4<\/p>\n<p>5. Number of tautomers: none<\/p>\n<p>6. Topological molecule polar surface area 18.5<\/p>\n<p>7. Number of heavy atoms: 21<\/p>\n<p>8. Surface charge: 0<\/p>\n<p>9. Complexity: 279<\/p>\n<p>10. Number of isotope atoms: 0<\/p>\n<p>11. Determine the number of atomic stereocenters: 0<\/p>\n<p>12. Uncertain number of atomic stereocenters: 0<\/p>\n<p>13. Determine the number of chemical bond stereocenters: 0  <\/p>\n<p>14. Number of uncertain chemical bond stereocenters: 0<\/p>\n<p>15. Number of covalent bond units: 1<\/p>\n<\/p>\n<h2 id=\"xz\">Properties and stability<\/h2>\n<p>\n     Mildly irritating to rabbit skin and eyes.\n     <\/p>\n<h2 id=\"zc\">Storage method<\/h2>\n<p><p>Store in a cool, ventilated and dry place, and do not mix with food, feed, beverages and other items.  <\/p>\n<\/p>\n<h2 id=\"hc\">Synthesis method<\/h2>\n<p><p>Prepared from the condensation of anisole and trichloroacetaldehyde.  <\/p>\n<p><span style=\"font-family:Arial\">Methoxychlor is produced by condensing anisole and trichloroacetaldehyde in the presence of fuming sulfuric acid or aluminum trichloride.  <br \/><\/span><\/p>\n<\/p>\n<h2 id=\"yt\">Purpose<\/h2>\n<p><p>1. An organochlorine pesticide.  This product is a non-systemic contact and stomach poisoning insecticide with slight aphidicide or acaricidal activity.  Its biological activity range is roughly the same as that of DDT.  Because it has little or no tendency to accumulate in body fat or be secreted into milk, it is recommended for fly control in dairies and dairy cows.  This product can also be used to prevent and control household sanitary pests, animal ectoparasites, vegetable and fruit tree pests, replacing DDT.  The maximum allowable residual amount is: 2 mg\/kg for grain, 14 mg\/kg for fruit trees, and 100 mg\/kg for feed.  The ban period before harvest is 7 to 21 days.  For example, when using 25% EC to control poplar loopers and aphid weevils in poplar and jujube trees, spray at 625 to 1250 mg\/L.  <\/p>\n<p>2.<span style=\"font-family:Arial\">Organochlorine pesticides.  It has contact and stomach poisoning effects, no systemic effect, wide insecticidal spectrum, low toxicity to humans and animals, no cumulative effect in the organism, and is easily decomposed by multifunctional oxidase and converted into water-soluble non-toxic excreta.  It can be used for field crops, fruit trees, vegetables and other crops to control corn borers, bridge-building insects, bean beetles, pea weevils, fruit tree borers, codling moths, Japanese beetles, small weevils, canopy caterpillars, and fruit<span>Flies, leafhoppers, stink bugs, vegetable leaf flea beetles, diamondback moths, cucumbers, seed flies and other pests. It can also be used to control ectoparasites and sanitary pests in livestock.  <\/span><\/span><\/p>\n<\/p>\n<p>     extended-reading:<a href=\"https:\/\/www.cyclohexylamine.net\/high-quality-triethylenediamine-cas-280-57-9-dabco-teda\/\">https:\/\/www.cyclohexylamine.net\/high-quality-triethylenediamine-cas-280-57-9-dabco-teda\/<\/a><\/br>extended-reading:<a href=\"https:\/\/www.cyclohexylamine.net\/2-2-dimethylaminoethoxyethanol\/\">https:\/\/www.cyclohexylamine.net\/2-2-dimethylaminoethoxyethanol\/<\/a><\/br>extended-reading:<a href=\"https:\/\/www.cyclohexylamine.net\/pc-12\/\">https:\/\/www.cyclohexylamine.net\/pc-12\/<\/a><\/br>extended-reading:<a href=\"https:\/\/www.newtopchem.com\/archives\/45053\">https:\/\/www.newtopchem.com\/archives\/45053<\/a><\/br>extended-reading:<a href=\"https:\/\/www.newtopchem.com\/archives\/41215\">https:\/\/www.newtopchem.com\/archives\/41215<\/a><\/br>extended-reading:<a href=\"https:\/\/www.newtopchem.com\/archives\/44906\">https:\/\/www.newtopchem.com\/archives\/44906<\/a><\/br>extended-reading:<a href=\"https:\/\/www.newtopchem.com\/archives\/44424\">https:\/\/www.newtopchem.com\/archives\/44424<\/a><\/br>extended-reading:<a href=\"https:\/\/www.bdmaee.net\/catalyst-a400-a400-polyurethane-catalyst-a400\/\">https:\/\/www.bdmaee.net\/catalyst-a400-a400-polyurethane-catalyst-a400\/<\/a><\/br>extended-reading:<a href=\"https:\/\/www.bdmaee.net\/cas-136-53-8\/\">https:\/\/www.bdmaee.net\/cas-136-53-8\/<\/a><\/br>extended-reading:<a href=\"https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/31-5.jpg\">https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/31-5.jpg<\/a><\/p>\n","protected":false,"gt_translate_keys":[{"key":"rendered","format":"html"}]},"excerpt":{"rendered":"<p>Structural formula Business number 01H1 Molecular formu&#8230;<\/p>\n","protected":false,"gt_translate_keys":[{"key":"rendered","format":"html"}]},"author":1,"featured_media":48046,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[6],"tags":[15095],"gt_translate_keys":[{"key":"link","format":"url"}],"_links":{"self":[{"href":"http:\/\/www.newtopchem.com\/wp-json\/wp\/v2\/posts\/48047"}],"collection":[{"href":"http:\/\/www.newtopchem.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.newtopchem.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.newtopchem.com\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/www.newtopchem.com\/wp-json\/wp\/v2\/comments?post=48047"}],"version-history":[{"count":0,"href":"http:\/\/www.newtopchem.com\/wp-json\/wp\/v2\/posts\/48047\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.newtopchem.com\/wp-json\/wp\/v2\/media\/48046"}],"wp:attachment":[{"href":"http:\/\/www.newtopchem.com\/wp-json\/wp\/v2\/media?parent=48047"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.newtopchem.com\/wp-json\/wp\/v2\/categories?post=48047"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.newtopchem.com\/wp-json\/wp\/v2\/tags?post=48047"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}